CAS No. 84418-43-9
Chemical Name: 9-Fluorenylmethyl carbamate
Synonyms: FMOC-NH2;FMOC-AMIDE;9-Fluorenylcarbamate;9-Fluorenylmethyl ca;9-Fluorenemethane Resin;9-FLUORENYLMETHYL CARBAMATE;9-Fluorenylmethyl carbamate ,98%;9-(FLUORENYLMETHYLCARBONYL) AMIDE;N-(9-FLUORENYLMETHOXYCARBONYL)AMIDE;(9H-Fluoren-9-Ylmethoxy)Carboxamide
CBNumber: CB7378720
Molecular Formula: C15H13NO2
Formula Weight: 239.27
MOL File: 84418-43-9.mol
A atypical abstraction of abject admeasurement for convalescent the photosensitivity of base-sensitive abstracts is declared by presenting the autocatalytic transformation of 9-fluorenylmethyl carbamates to aliphatic amines. A 9-fluorenylmethyl carbamate, as a abject amplifier, was subjected to a base-catalysed breach acknowledgment to deliver the agnate amine, which can again act as a agitator for decomposing ancestor molecules, arch to autocatalytic decomposition. Consequently, the amine is generated from an equimolar bulk of the carbamate application a catalytic bulk of the aforementioned amine. 1-(9-Fluorenylmethoxycarbonyl)piperidine and 1-(9-fluorenylmethoxycarbonyl)cyclohexylamine were acceptable as abject amplifiers because of their thermal adherence beneath aloof altitude and top base-catalytic reactivity. On the abject of the results, 1,3-bis[1-(9-fluorenylmethoxycarbonyl)-4-piperidyl]propane and 1,6-bis[(9-fluorenylmethoxy)carbonylamino]hexane were advised as abject amplifiers which deliver aliphatic diamines to crosslink poly(glycidyl methacrylate) photochemically in the attendance of a photobase generator. Addition of the abject amplifiers resulted in a apparent advance of the photosensitivity characteristics of the polymer by a agency of 16 and 50, respectively.
Properties
Melting point :201-204 ºC
Read more: buy 9-Fluorenylmethyl carbamate
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